Oxidation of crotyl alcohol by N-chloro-4-methylbenzene sulphonamide in acidic medium and in alkaline media in the presence of os(VIII) catalyst-a kinetic pathway

Authors

PRIYAMVADA SHARMA
RIYA SAILANI
ANITA MEENA
CHANDRA LATA KHANDELWAL

DOI

10.3906/kim-2003-67

Abstract

The kinetic pathway of oxidation of crotyl alcohol by sodium salt of $N$-chloro-4-methylbenzene sulphonamide (chloramine-T) in acidic and alkaline medium has been studied. The speciation of chloramine-T has been made to suggest a proper and reasonable reaction mechanism. The thermodynamic quantities such as activation energy and activation entropy are evaluated in acidic as well as in catalysed alkaline medium. An anticipated reaction mechanism has been suggested.

Keywords

Electron transfer reaction, reaction kinetics, mechanism, osmium(VIII) catalysis, crotyl alcohol, chloramine-T

First Page

950

Last Page

970

Recommended Citation

SHARMA, PRIYAMVADA; SAILANI, RIYA; MEENA, ANITA; and KHANDELWAL, CHANDRA LATA (2020) "Oxidation of crotyl alcohol by N-chloro-4-methylbenzene sulphonamide in acidic medium and in alkaline media in the presence of os(VIII) catalyst-a kinetic pathway," Turkish Journal of Chemistry: Vol. 44: No. 4, Article 7. https://doi.org/10.3906/kim-2003-67
Available at: https://journals.tubitak.gov.tr/chem/vol44/iss4/7