Kinetics of silver(I)-catalyzed oxidation of allyl alcohol by peroxodiphosphate inacetate buffers

Authors

PRIYAMVADA SHARMA
RIYA SAILANI
DEEPMALA PAREEK
CHANDRA LATA KHANDELWAL

DOI

10.3906/kim-1701-32

Abstract

The kinetics and mechanism of silver(I)-catalyzed oxidation of allyl alcohol with peroxodiphosphate in acetate buffers have been studied. The rate is independent of allyl alcohol concentration. The effect of other reaction parameters such as hydrogen and acetate ions has also been studied. The rate law accounting for all experimental observations corresponds to the proposed mechanism. The energy and entropy of activation have also been evaluated by employing Eyring plots.

Keywords

Kinetics, mechanism, oxidation, allyl alcohol, peroxodiphosphate

First Page

158

Last Page

169

Recommended Citation

SHARMA, PRIYAMVADA; SAILANI, RIYA; PAREEK, DEEPMALA; and KHANDELWAL, CHANDRA LATA (2018) "Kinetics of silver(I)-catalyzed oxidation of allyl alcohol by peroxodiphosphate inacetate buffers," Turkish Journal of Chemistry: Vol. 42: No. 1, Article 14. https://doi.org/10.3906/kim-1701-32
Available at: https://journals.tubitak.gov.tr/chem/vol42/iss1/14