Turkish Journal of Chemistry
Abstract
New furanoside-based NHC precursor salts (2) were synthesized using amino alcohols from the chloralose derivatives of glucose (a), galactose (b), and mannose (c). The novel compounds were fully characterized by $^{1}$H NMR, $^{13}$C NMR, and elemental analyses. The catalytic activities of these salts were tested in the arylation of aldehydes as catalysts that were generated in situ from [RhCl(COD)]$_{2}$. In addition, 2a was converted to the rhodium complex 3a in order to compare the results obtained in situ. The newly synthesized compounds were very efficient in terms of yield; nevertheless they did not exhibit a chiral induction.
DOI
10.3906/kim-1603-95
Keywords
N-heterocyclic carbene, carbohydrates, arylation of aldehydes, rhodium
First Page
689
Last Page
697
Recommended Citation
DENİZALTI, S, TELLİ, F. Ç, YILDIRAN, S, SALMAN, A. Y, & ÇETİNKAYA, B (2016). Newly synthesized furanoside-based NHC ligands for the arylation of aldehydes. Turkish Journal of Chemistry 40 (5): 689-697. https://doi.org/10.3906/kim-1603-95
