Turkish Journal of Chemistry
Abstract
In this study peripherally tetra-substituted metal-free, metallophthalocyanines bearing (3,4-dimethoxybenzyl) oxy groups have been synthesized and characterized. Electrochemical properties of novel phthalocyanines 4, 5, 6, and 7 were determined by cyclic and square wave voltammetry in order to define their possible applications in different electrochemical technologies. Co^{II} and Ti^{IV}O metal ions behave as redox active cations in the core of the CoPc and TiOPc complexes, respectively. Voltammetric studies revealed that phthalocyanines have reversible/irreversible redox processes, which are the main requirement for the technological usage of these compounds.
DOI
10.3906/kim-1408-71
Keywords
Phthalocyanine, oxotitanium, cobalt, electrochemistry, voltammetry
First Page
347
Last Page
358
Recommended Citation
ÖMEROĞLU, İPEK and BIYIKLIOĞLU, ZEKERİYA
(2015)
"Synthesis and electrochemistry of phthalocyanines bearing [(3,4-dimethoxybenzyl)oxy] groups,"
Turkish Journal of Chemistry: Vol. 39:
No.
2, Article 13.
https://doi.org/10.3906/kim-1408-71
Available at:
https://journals.tubitak.gov.tr/chem/vol39/iss2/13
