Turkish Journal of Chemistry
DOI
-
Abstract
The adsorption of n-butylamine from its solution in cyclohexane on acid-activated and thermally treated Kütahya/Turkey bentonite (KB) samples was followed using a UV-VIS spectrophotometric method. The experimental data were evaluated by the Langmuir adsorption equation and the total number of surface acid centers (n_{m/mol} g^{-1}) was determined. The variation in n_m values as a function of the mass percent of H_2SO_4 used in activation (10%-70%) and its correlation with variations in surface area (A) and pore volume (V) as a function of the mass percent of H_2SO_4 were investigated for acid- activated KB samples. The variation in n_m values as a function of thermal treatment temperature (200 °C-1300 °C) and its correlation with variations in A and V as a function of thermal treatment temperature were investigated for thermally treated KB samples and the results are discussed.
Keywords
Acid activation, bentonite, n-butylamine, pore volume, surface acidity, surface area, thermal treatment
First Page
675
Last Page
682
Recommended Citation
ALEMDAROĞLU, TÜLAY; AKKUŞ, GÜLCAN; ONAL, MÜŞERREF; and SARIKAYA, YÜKSEL (2003) "Investigation of the Surface Acidity of a Bentonite Modified by Acid Activation and Thermal Treatment," Turkish Journal of Chemistry: Vol. 27: No. 6, Article 2. Available at: https://journals.tubitak.gov.tr/chem/vol27/iss6/2
