Turkish Journal of Chemistry
DOI
-
Abstract
Cyclic voltammetry (CV) and preparative electrolysis techniques were used to investigate the reduction of nitrobenzene into (NB) p-aminophenol (p-Ap). The electrodes used in CV experiments were glassy carbon (GC), TiO_{2}/Ti, Sn and Pb. The preparative electrolyses were carried out by the use of Pb, Sn, carbon cloth and TiO_{2}/Ti electrodes. The CV data were evaluated according to Nicholson-Shain criteria, and it was deduced that the reductions on TiO_{2}/Ti and GC electrodes were irreversible and monitored by an electrochemical-chemical-electrochemical mechanism. No reduction peak was observed with Sn and Pb electrodes. Preparative electrolyses were carried out under current-controlled conditions in the presence and absence of solvent. The best yield of (p-Ap) was obtained with a circulating neat NB electrolysis system on a TiO_{2}/Ti electrode.
Keywords
Nitrobenzene, p-aminophenol, cyclic voltammetry, continuous electrolysis, electrolytic reduction.
First Page
501
Last Page
512
Recommended Citation
POLAT, KAMRAN (2003) "A Novel, Semi-Pilot Scale Electrolysis System for the Production of p-Aminophenol," Turkish Journal of Chemistry: Vol. 27: No. 4, Article 11. Available at: https://journals.tubitak.gov.tr/chem/vol27/iss4/11
