Turkish Journal of Chemistry
Bifunctional Allyl-Sulphonium Salt as a Novel Addition--Fragmentation Agent for Photoinitiated Cationic Polymerization
Bifunctional allyl tetrahydrothiophenium hexafluoroantimonate was synthesized via a one-pot reaction of 3-chloro-2-chloromethylpropene with thiophene in the presence of sodium hexafluoroantimonate. The initiation capability of this salt, in conjunction with a photochemical free radical source such as 2,2-dimethoxy-2-phenyl acetophenone and benzophenone, via an addition-fragmentation mechanism in the cationic polymerization of cyclohexene oxide and butyl vinyl ether is investigated.
KÜÇÜKTÖMBEKİCİ, UTKU; DEĞİRMENCİ, MUSTAFA; and YAĞCI, YUSUF (2002) "Bifunctional Allyl-Sulphonium Salt as a Novel Addition--Fragmentation Agent for Photoinitiated Cationic Polymerization," Turkish Journal of Chemistry: Vol. 26: No. 5, Article 19. Available at: https://journals.tubitak.gov.tr/chem/vol26/iss5/19