Turkish Journal of Chemistry
Abstract
Bifunctional allyl tetrahydrothiophenium hexafluoroantimonate was synthesized via a one-pot reaction of 3-chloro-2-chloromethylpropene with thiophene in the presence of sodium hexafluoroantimonate. The initiation capability of this salt, in conjunction with a photochemical free radical source such as 2,2-dimethoxy-2-phenyl acetophenone and benzophenone, via an addition-fragmentation mechanism in the cationic polymerization of cyclohexene oxide and butyl vinyl ether is investigated.
DOI
-
First Page
793
Last Page
800
Recommended Citation
KÜÇÜKTÖMBEKİCİ, U, DEĞİRMENCİ, M, & YAĞCI, Y (2002). Bifunctional Allyl-Sulphonium Salt as a Novel Addition--Fragmentation Agent for Photoinitiated Cationic Polymerization. Turkish Journal of Chemistry 26 (5): 793-800. https://doi.org/-