Turkish Journal of Chemistry
DOI
-
Abstract
Ethylenediamine-N,N'-ditetradecyl-N,N'-diacetic acid (EDDAT) was synthesized for the solvent extraction of La$^{3+}$. EDDAT was prepared from ethylenediamine-N,N'-diacetic acid (EDDA) and tetradecyl bromide in a basic n-amylalcohol-ethanol-water solvent system. The structure of this new extracting reagent was identified according to spectroscopic data, i.e. $^{13}$C NMR, $^1$H NMR, and elemental analysis results. The solvent extraction of La$^{3+}$ with EDDAT in dichloromethane was studied as a function of parameters of the aqueous and organic phases. The optimal extraction conditions were determined. The extraction yield increased with a decrease in hydrogen ions in the aqueous phase. Stripping of the La$^{3+}$ loaded organic phase was achieved with HCl aqueous solution. The effect of stripping as a function of the HCl concentration was also studied.
First Page
373
Last Page
378
Recommended Citation
YURDAKOÇ, Mürüvvet and HOŞGÖREN, Halil (1998) "Solvent Extraction of La^{3+} withEthylenediamine-N,N'-ditetradecyl-N,N'-diacetic Acid(EDDAT) in Dichloromethane," Turkish Journal of Chemistry: Vol. 22: No. 4, Article 9. Available at: https://journals.tubitak.gov.tr/chem/vol22/iss4/9
