Density functional theory calculations of equilibrium oxygen isotope fractionation between borate minerals and aqueous fluids

Authors

Hai-Zhen Wei
Martin Palmer
Jun-Lin Wang
Shao-Yong Jiang
Simon V. Hohl
Yuan-Feng Zhu
Chun Huan
Miao-Miao Zhang
YEŞİM YÜCEL ÖZTÜRK

DOI

10.55730/1300-0985.1873

Abstract

Borax, ulexite, and colemanite minerals are by far the most important economic source of boron and occur almost exclusively in nonmarine evaporite deposits. While much is known about the geological setting in which they are found, surprisingly little is known about the chemical and physical properties of the brines from which they are formed. Oxygen isotope studies have the potential to reveal important new information regarding borate formation, but unlike most other common oxygen-bearing salts precipitated from brines, there are no experimental data regarding the oxygen isotope fractionation factors between borates and brines. As a first attempt to address this gap in our understanding we have determined Δ¹⁸O_borate-water values between 0 and 100 °C using density functional theory calculations (DFT). These results predicted Δ¹⁸O_borate-water values of 12.87, 22.32, and 17.5‰ at 25 °C for borax, colemanite and ulexite, respectively.

Keywords

Oxygen isotopes, nonmarine evaporites, borax, ulexite, colemanite, borate deposits

First Page

764

Last Page

771

Recommended Citation

Wei, Hai-Zhen; Palmer, Martin; Wang, Jun-Lin; Jiang, Shao-Yong; Hohl, Simon V.; Zhu, Yuan-Feng; Huan, Chun; Zhang, Miao-Miao; and ÖZTÜRK, YEŞİM YÜCEL (2023) "Density functional theory calculations of equilibrium oxygen isotope fractionation between borate minerals and aqueous fluids," Turkish Journal of Earth Sciences: Vol. 32: No. 6, Article 4. https://doi.org/10.55730/1300-0985.1873
Available at: https://journals.tubitak.gov.tr/earth/vol32/iss6/4