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Turkish Journal of Chemistry

Abstract

Advancements in cost-effective and efficient alternative energy sources are critical for socioeconomic development. In this study, Iron-based metal–organic framework (Fe-MOF) electrocatalyst was fabricated using an Fe salt and ligand. Several surface characterization methods, including Fourier Transform-Infrared Spectroscopy (FTIR), Scanning Electron Microscope (SEM), and X-ray diffraction (XRD), were used to characterize the electrocatalyst. Additionally, using Chronoamperometry (CA), Electrochemical Impedance Spectroscopy (EIS), Linear Sweep Voltammetry (LSV), and Cyclic Voltammetry (CV), the electrocatalytic behaviour in a cathodic reaction in PEMFCs is investigated. The study showed the material’s exceptional chemical or surface stability, and great surface morphology of the material that facilitated the cathodic reaction. This study reported the development of a Platinum Group Metal (PGM)-free potential electrocatalyst for oxygen reduction reaction at the cathode in Proton Exchange Membrane Fuel Cells (PEMFCs).

Author ORCID Identifier

SUSMITA SINGH: 0000-0002-6290-7949

TANYA NISHAD: 0009-0001-2345-6233

DEBASMITA PAUL: 0009-0002-6901-6150

SUMI GANGULY: 0000-0001-6407-439X

SOUMYABRATA GOSWAMI: 0000-0002-9646-1439

DOI

10.55730/1300-0527.3783

Keywords

Metal Organic Framework (MOF), Proton Exchange Membrane Fuel Cells (PEMFCs), electrocatalyst, nanomaterial, Oxygen Reduction Reaction (ORR), greener alternative

First Page

102

Last Page

111

Publisher

The Scientific and Technological Research Council of Türkiye (TÜBİTAK)

Creative Commons License

Creative Commons Attribution 4.0 International License
This work is licensed under a Creative Commons Attribution 4.0 International License.

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Chemistry Commons

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