Turkish Journal of Chemistry
Abstract
The formation of a heterogeneous junction between photocatalysts may be a potential solution for removing medicinal compounds from wastewater, which is crucial due to the environmental and health risks. The present study aims to investigate the efficacy of UiO-66/AgInS2 p–n junction photocatalyst—a Zr-based metal-organic framework—in degradation of enrofloxacin (ENR) antibiotic using visible light. UiO-66, AgInS2 (AIS), and UiO-66/AIS semiconductors were characterized using various techniques. The comparative analysis of particle structural parameters utilized diverse methodologies, and response surface methodology (RSM) was applied for the optimization of ENR degradation. The degradation kinetics of ENR were investigated. We identified UiO-66/AIS as a p–n junction semiconductor with a 1.71 eV direct band gap. Mott–Schottky analysis yielded ECB and EVB values of 1.72 V and 0.64 V for UiO-66 and −0.5 V and 1.05 V for AIS, respectively. The size-strain plot (SSP) method was determined to be the most effective in determining crystal dimensions, and a UiO-66/AIS p–n junction was instrumental in achieving 94.32% ENR degradation in a very short time using a pseudo-second-order kinetic model. The findings of this empirical study indicate that the UiO-66/AIS p–n junction has demonstrated exceptional efficiency in the removal of the ENR drug.
Author ORCID Identifier
SAJEDEH SADAT HASHEMIPOOR: 0009-0007-6491-0328
REZA FAZAELI: 0000-0001-6498-2048
HAMID REZA MOGHADAM ZADEH: 0009-0005-9756-8907
MEHDI ARJOMAND: 0000-0003-1587-6892
DOI
10.55730/1300-0527.3747
Keywords
UiO-66/AgInS2, photocatalysis, degradation, enrofloxacin, Box-Behnken design
First Page
495
Last Page
510
Publisher
The Scientific and Technological Research Council of Türkiye (TÜBİTAK)
Creative Commons License
This work is licensed under a Creative Commons Attribution 4.0 International License.
Recommended Citation
HASHEMIPOOR, S, FAZAELI, R, MOGHADAM ZADEH, H, & ARJOMAND, M (2025). A novel p–n junction UiO-66/AgInS2 for photodegradation of enrofloxacin under visible light. Turkish Journal of Chemistry 49 (4): 495-510. https://doi.org/10.55730/1300-0527.3747
