Turkish Journal of Chemistry
Abstract
This study’s main goal was to produce a user-friendly dispersive micro solid phase extraction (dmSPE) technique with a MIL-53(Al)@BaTiO3 nanocomposite for the extraction and preconcentration of cadmium (Cd) in various seafood matrices, followed by using high-resolution continuum source flame atomic absorption spectrometry (HR-CS-FAAS). The MIL-53(Al)@BaTiO3 nanocomposite was synthesized and characterized using a range of techniques, including Fourier-transform infrared spectroscopy, field emission scanning electron microscopy, scanning transmission electron microscopy, X-ray diffraction, and Brunauer-Emmett-Teller analysis. The dmSPE technique involved the dispersion of the MIL-53(Al)@BaTiO3 material in the sample solution, followed by its separation from the sample matrix. The optimized method exhibited a linear range of 3.6–250 μg L−1, a limit of detection (LOD) of 1.2 μg L−1, and a preconcentration factor of 80. Two different certified reference materials were used to ensure the validation of developed method. The method was applied to different seafood samples.
Author ORCID Identifier
MUSTAFA SOYLAK: 0000-0002-1017-0244
EDA BORA: 0000-0002-0187-5015
FURKAN UZCAN: 0000-0001-6831-3087
DOI
10.55730/1300-0527.3733
Keywords
Cadmium, seafoods, micro solid phase extraction, nanocomposite
First Page
336
Last Page
345
Publisher
The Scientific and Technological Research Council of Türkiye (TÜBİTAK)
Creative Commons License
This work is licensed under a Creative Commons Attribution 4.0 International License.
Recommended Citation
SOYLAK, M, BORA, E, & UZCAN, F (2025). Dispersive micro solid phase extraction of cadmium on MIL-53(Al)@BaTiO3 nanocomposite from seafood samples. Turkish Journal of Chemistry 49 (3): 336-345. https://doi.org/10.55730/1300-0527.3733
