The synthesis and characterization of a novel covalent organic polymer cobalt (II) phthalocyanine (ATA-100) including tetra amino group is described for the first time. This covalent organic polymer (COP) is characterized by FTIR, TGA, RAMAN, PXRD, and SEM-EDS. The developed sensor is tested for acetone, ethyl butyrate, n-hexane, chloroform, and n-butyraldehyde in a range of 80-10,900 ppm. ATA-100 showed the highest sensitivity for ethyl butyrate. The results have confirmed the possibility of utilizing ATA-100 COP-based surface acoustic wave (SAW) sensors for a wide variety of applications, including indoor air quality and environmental monitoring of volatile organic compounds (VOCs).
Phthalocyanine (Pc), covalent organic polymer (COP), volatile organic compounds (VOCs), sensor, surface acoustic wave (SAW)
GÜNEY, GÜNSELİ; KAPLAN, GÜLAY ALTINDEMİR; TAŞALTIN, CİHAT; and GÜROL, İLKE
"Advanced tetra amino (ATA-100) cobalt(II) phthalocyanine-based metallo-covalent organic polymer for sensitively detecting volatile organic compounds,"
Turkish Journal of Chemistry: Vol. 47:
5, Article 20.
Available at: https://journals.tubitak.gov.tr/chem/vol47/iss5/20