Advanced tetra amino (ATA-100) cobalt(II) phthalocyanine-based metallo-covalent organic polymer for sensitively detecting volatile organic compounds

Authors

GÜNSELİ GÜNEY
GÜLAY ALTINDEMİR KAPLAN
CİHAT TAŞALTIN
İLKE GÜROL

Abstract

The synthesis and characterization of a novel covalent organic polymer cobalt (II) phthalocyanine (ATA-100) including tetra amino group is described for the first time. This covalent organic polymer (COP) is characterized by FTIR, TGA, RAMAN, PXRD, and SEM-EDS. The developed sensor is tested for acetone, ethyl butyrate, n-hexane, chloroform, and n-butyraldehyde in a range of 80-10,900 ppm. ATA-100 showed the highest sensitivity for ethyl butyrate. The results have confirmed the possibility of utilizing ATA-100 COP-based surface acoustic wave (SAW) sensors for a wide variety of applications, including indoor air quality and environmental monitoring of volatile organic compounds (VOCs).

DOI

10.55730/1300-0527.3600

Keywords

Phthalocyanine (Pc), covalent organic polymer (COP), volatile organic compounds (VOCs), sensor, surface acoustic wave (SAW)

First Page

1138

Last Page

1148

Recommended Citation

GÜNEY, GÜNSELİ; KAPLAN, GÜLAY ALTINDEMİR; TAŞALTIN, CİHAT; and GÜROL, İLKE (2023) "Advanced tetra amino (ATA-100) cobalt(II) phthalocyanine-based metallo-covalent organic polymer for sensitively detecting volatile organic compounds," Turkish Journal of Chemistry: Vol. 47: No. 5, Article 20. https://doi.org/10.55730/1300-0527.3600
Available at: https://journals.tubitak.gov.tr/chem/vol47/iss5/20