Turkish Journal of Chemistry
DOI
10.55730/1300-0527.3446
Abstract
Known 1,6-di(thiophen-2-yl)hexane-1,6-dione (2) and novel 1,7-di(thiophen-2-yl)heptane-1,7-dione (4) were obtained from the reactions of thiophene with the corresponding diacyl chlorides. Furthermore, compounds with furan and pyrrole units in place of thiophene units in compound 2 were obtained in the same way. Bromination of 2 and 4 gave bromides regioselectively. The reaction of each of the compounds 2 and 4 in HOAc medium yielded cyclocondensation products. In total, four known and eleven novel compounds were synthesized.
First Page
1397
Last Page
1404
Recommended Citation
ARTUNÇ, TEKİN and MENZEK, ABDULLAH
(2022)
"Synthesis and reactions of di(thiophen-2-yl)alkane diones: Cyclocondensation,"
Turkish Journal of Chemistry: Vol. 46:
No.
5, Article 4.
https://doi.org/10.55730/1300-0527.3446
Available at:
https://journals.tubitak.gov.tr/chem/vol46/iss5/4
