New ligand based on p-tertbutyltetrathiacalixarene blocked in 1,3-alternate conformation, was achieved via a multistep synthesis with the introduction of thiomethylpropoxy groups on the lower rim which leads to a neutral tecton. The combination of this p-tertbutyltetrathiacalixarene (p-TCA-2), in 1, 3-alternate imposed conformation, with tetrahedral Ag(I)SbF6 salt, leads to the formation of neutral, new 2-D coordination network, which was structurally investigated in the solid state by X-ray diffraction methods on a single crystal.
KILIÇ, HURİYE AKDAŞ; GRAF, ERNEST; HOSSEİNİ, MİR WAİS; and KYRİTSAKAS, NATHALİE
"New 2-D silver(I) coordination network constructed from thiomethyl group-substituted p-tert-butylthiacalixarene,"
Turkish Journal of Chemistry: Vol. 46:
5, Article 17.
Available at: https://journals.tubitak.gov.tr/chem/vol46/iss5/17