New 2-D silver(I) coordination network constructed from thiomethyl group-substituted p-tert-butylthiacalix[4]arene

Authors

HURİYE AKDAŞ KILIÇ
ERNEST GRAF
MİR WAİS HOSSEİNİ
NATHALİE KYRİTSAKAS

DOI

10.55730/1300-0527.3459

Abstract

New ligand based on p-tertbutyltetrathiacalix[4]arene blocked in 1,3-alternate conformation, was achieved via a multistep synthesis with the introduction of thiomethylpropoxy groups on the lower rim which leads to a neutral tecton. The combination of this p-tertbutyltetrathiacalix[4]arene (p-TCA-2), in 1, 3-alternate imposed conformation, with tetrahedral Ag(I)SbF₆ salt, leads to the formation of neutral, new 2-D coordination network, which was structurally investigated in the solid state by X-ray diffraction methods on a single crystal.

Keywords

Molecular networks, coordination polymer, thiacalix[4]arene, X-ray structure, thioether

First Page

1541

Last Page

1547

Recommended Citation

KILIÇ, HURİYE AKDAŞ; GRAF, ERNEST; HOSSEİNİ, MİR WAİS; and KYRİTSAKAS, NATHALİE (2022) "New 2-D silver(I) coordination network constructed from thiomethyl group-substituted p-tert-butylthiacalix[4]arene," Turkish Journal of Chemistry: Vol. 46: No. 5, Article 17. https://doi.org/10.55730/1300-0527.3459
Available at: https://journals.tubitak.gov.tr/chem/vol46/iss5/17