1-D and 2-D coordination networks based on tetrathiacalix[4]arene derivative generated with mercury and cobalt salts

Authors

HURİYE AKDAŞ KILIÇ
ERNEST GRAF
MİR WAİS HOSSEİNİ
NATHALİE KYRİTSAKAS

DOI

10.55730/1300-0527.3431

Abstract

The combination of four iso-nicotinate appended tetrathiacalix[4]arene (TCA-1) in 1,2-alternate imposed conformation behaving as neutral tectons with Co(II)Cl2 and Hg(II)Cl2 metallic salts, leads to the formation of neutral, new coordination networks. Indeed, the tetrasubstituted TCA-1 derivative leads to a 1D coordination polymer with Co(II)Cl2 and a 2D grid-like network with, Hg(II)Cl2. The effect of the nature of the metal used on the dimensionality was demonstrated by X-ray diffraction studies on a single crystal.

Keywords

Molecular networks, coordination polymer, thiacalix[4]arene, X-ray structure

First Page

1245

Last Page

1252

Recommended Citation

KILIÇ, HURİYE AKDAŞ; GRAF, ERNEST; HOSSEİNİ, MİR WAİS; and KYRİTSAKAS, NATHALİE (2022) "1-D and 2-D coordination networks based on tetrathiacalix[4]arene derivative generated with mercury and cobalt salts," Turkish Journal of Chemistry: Vol. 46: No. 4, Article 27. https://doi.org/10.55730/1300-0527.3431
Available at: https://journals.tubitak.gov.tr/chem/vol46/iss4/27