Turkish Journal of Chemistry
Abstract
The combination of four iso-nicotinate appended tetrathiacalix[4]arene (TCA-1) in 1,2-alternate imposed conformation behaving as neutral tectons with Co(II)Cl2 and Hg(II)Cl2 metallic salts, leads to the formation of neutral, new coordination networks. Indeed, the tetrasubstituted TCA-1 derivative leads to a 1D coordination polymer with Co(II)Cl2 and a 2D grid-like network with, Hg(II)Cl2. The effect of the nature of the metal used on the dimensionality was demonstrated by X-ray diffraction studies on a single crystal.
DOI
10.55730/1300-0527.3431
Keywords
Molecular networks, coordination polymer, thiacalix[4]arene, X-ray structure
First Page
1245
Last Page
1252
Recommended Citation
KILIÇ, H. A, GRAF, E, HOSSEİNİ, M. W, & KYRİTSAKAS, N (2022). 1-D and 2-D coordination networks based on tetrathiacalix[4]arene derivative generated with mercury and cobalt salts. Turkish Journal of Chemistry 46 (4): 1245-1252. https://doi.org/10.55730/1300-0527.3431
