Turkish Journal of Chemistry
Abstract
3-[5-(diethylamino)-2-formylphenoxy]phthalonitrile (n-TY-CN), metallophthalocyanines n-TY-Co, n-TY-Cu, and n-TY-Mn bearing [5-(diethylamino)-2-formylphenoxy] groups at nonperipheral positions were prepared for the first time. These compounds were characterized with IR, NMR (only for n-TY-CN), mass and UV-vis (except n-TY-CN) spectroscopy. Voltammetric characterizations of n-TY-Co, n-TY-Cu, and n-TY-Mn revealed that while n-TY-Co, n-TY-Cu, and n-TY-Mn showed characteristic Pc ring and/or metal-based reduction reaction, n-TY-Co, n-TY-Cu, and n-TY-Mn were coated on the working electrode during the oxidation processes owing to the cationic electropolymerizations of the [5-(diethylamino)-2-formylphenoxy] substituents.
DOI
10.3906/kim-2007-47
Keywords
Synthesis, diethylamino, phthalocyanine, electrochemistry
First Page
17
Last Page
25
Recommended Citation
KELEŞ, T, ÜNLÜER, D, BIYIKLIOĞLU, Z, & ÜNVER, Y (2021). Synthesis of nonperipherally tetra-[5-(diethylamino)-2-formylphenoxy] substituted metallophthalocyanines and their electrochemistry. Turkish Journal of Chemistry 45 (1): 17-25. https://doi.org/10.3906/kim-2007-47
