Synthesis of new cyclotriphosphazene derivatives bearing Schiff bases and theirthermal and absorbance properties

Authors

SEMİH DOĞAN
SÜREYYA OĞUZ TÜMAY
CEYLAN MUTLU BALCI
SERKAN YEŞİLOT
SERAP BEŞLİ

DOI

10.3906/kim-1905-60

Abstract

In this study, a series of cyclotriphosphazene derivatives containing a Schiff base (3a-3d) were synthesized by the reactions of hexachlorocyclotriphosphazene (1) with bis-aryl Schiff bases (2a-2d) having different terminal groups (H, F, Cl, and Br). The products (3a-3d) were characterized by elemental and mass analyses, FT-IR, and $^{1}$H, $^{13}$C, and 31 P NMR spectroscopies. Furthermore, the structure of compound 3a was also determined by X-ray crystallography. The thermal behaviors and the spectral properties of the new cyclotriphosphazene compounds (3a-3d) were investigated and the results were compared in the series.

Keywords

Cyclotriphosphazene, Schiff base, thermal stability, UV absorption, substituent effect

First Page

31

Last Page

47

Recommended Citation

DOĞAN, SEMİH; TÜMAY, SÜREYYA OĞUZ; BALCI, CEYLAN MUTLU; YEŞİLOT, SERKAN; and BEŞLİ, SERAP (2020) "Synthesis of new cyclotriphosphazene derivatives bearing Schiff bases and theirthermal and absorbance properties," Turkish Journal of Chemistry: Vol. 44: No. 1, Article 3. https://doi.org/10.3906/kim-1905-60
Available at: https://journals.tubitak.gov.tr/chem/vol44/iss1/3