Turkish Journal of Chemistry
Abstract
Coumarin-based chromogenic and fluorogenic dye 4 was designed and synthesized. The photophysical properties of 4 were determined in solvents with different polarities. Protonation affinity was determined by adding trifluoroacetic acid (TFA) to a dichloromethane solution of dye 4 utilizing the UV-Vis and fluorescence titration methods. The protonation region was investigated by using the $^{1}$H NMR method. Additionally, DFT and TDDFT studies were performed to support the structural and absorption spectral properties of 4.
DOI
10.3906/kim-1902-38
Keywords
Coumarin, benzilmonohydrazone, fluorescence dye, acidochromism, proton-sensitive dye
First Page
1086
Last Page
1097
Recommended Citation
AYDINER, BURCU
(2019)
"Coumarin-based benzilmonohydrazone as a new proton-sensitive fluorescence dye: synthesis and investigation of photophysical and acidochromic properties,"
Turkish Journal of Chemistry: Vol. 43:
No.
4, Article 9.
https://doi.org/10.3906/kim-1902-38
Available at:
https://journals.tubitak.gov.tr/chem/vol43/iss4/9
