Characterization and purification of 1,2,4-triazole-containing phthalocyanines synthesized by microwave method and structure elucidation by spectroscopic techniques

Authors

ASİYE NAS
ÜMİT DEMİRBAŞ
NURHAN GÜMRÜKÇÜOĞLU
HALİT KANTEKİN

DOI

10.3906/kim-1807-54

Abstract

The complexes of peripherally tetra-substituted metal-free (8), lead(II) 9), and zinc(II) (10) phthalocyanine derivatives were synthesized for the first time in this work. The structures of these new complex compounds have been elucidated using many spectral methods such as electronic absorption, FT-IR, $^{1}$H NMR, $^{13}$C NMR, elemental analysis, and mass spectra. The thermogravimetric behavior of compounds 8-10 was determined by thermogravimetric analysis method in addition to these spectral methods.

Keywords

Metallophthalocyanine, 1, 2, 4-triazole, 4-nitrophthalonitrile, thermogravimetric analysis, ethyl 4-methylben- zimidate

First Page

229

Last Page

238

Recommended Citation

NAS, ASİYE; DEMİRBAŞ, ÜMİT; GÜMRÜKÇÜOĞLU, NURHAN; and KANTEKİN, HALİT (2019) "Characterization and purification of 1,2,4-triazole-containing phthalocyanines synthesized by microwave method and structure elucidation by spectroscopic techniques," Turkish Journal of Chemistry: Vol. 43: No. 1, Article 19. https://doi.org/10.3906/kim-1807-54
Available at: https://journals.tubitak.gov.tr/chem/vol43/iss1/19