Turkish Journal of Chemistry
Abstract
New thermally stable metallo-phthalocyanines bearing dibenzoxanthenes as highly organo-solubilizing aromatic hydrocarbon substituents were successfully prepared by cyclotetramerization of corresponding phthalonitriles with anhydrous metal salts [Zn(CH$_{3}$COO)$_{2}$ and NiCl$_{2}$] in the presence of a catalytic amount of DBU in 2-(dimethylamino) ethanol. All of these phthalocyanines are soluble in some organic solvents such as DMF, DMSO, THF, CH$_{2}$Cl$_{2}$, and CHCl$_{3}$. Then we successfully prepared the poly(methyl methacrylate) (PMMA)/ZnPc/Al nanocomposite films by incorporating Al nanoparticles into a transparent PMMA/ZnPc matrix. The structure and morphology of nanocomposite films were studied using X-ray diffraction and scanning electron microscopy. The optical absorption spectra of PMMA/ZnPc/Al nanocomposite films showed red shifting in the Q-band in the polymeric matrix. The geometrical structure of two phthalocyanines was investigated at the RHF/3-21G* computational level.
DOI
10.3906/kim-1509-28
Keywords
Soluble metallophthalocyanine, dibenzoxanthene, aggregation, nanocomposite film, geometry optimization
First Page
602
Last Page
612
Recommended Citation
KARIMI, ALI REZA; JAFARZADEH, ZEINAB; SOURINIA, MEYSAM; ZENDEHNAM, AKBAR; KHODADADI, AZAM; DALIRNASAB, ZEINAB; SOLIMANNEJAD, MOHAMMAD; and ZOLGHARNEIN, PEYMAN
(2016)
"Synthesis and computational studies of new metallo-phthalocyanines bearing dibenzoxanthenes and evaluation of their optical properties in solution and solid PMMA/ZnPc/Al nanocomposite films,"
Turkish Journal of Chemistry: Vol. 40:
No.
4, Article 6.
https://doi.org/10.3906/kim-1509-28
Available at:
https://journals.tubitak.gov.tr/chem/vol40/iss4/6
