Abstract

$^{15}$N labeled soluble metallo- and metal-free phthalocyanines are described for the first time. The complexes were synthesized starting from phthalic anhydride derivatives using 98{\%} $^{15}$N enriched urea. The effects of the substitution pattern, aggregation, and coordinated metal on $^{15}$N chemical shifts in liquid state NMR were studied.

DOI

10.3906/kim-1506-8

Keywords

Phthalocyanines, $^{15}$N NMR, isotopic shifts, constitutional isomers

First Page

163

Last Page

173

Recommended Citation

ATSAY, A, GÜL, A, & KOÇAK, M (2016). Liquid state $^{15}$N NMR studies of $^{15}$N isotope labeled phthalocyanines. Turkish Journal of Chemistry 40 (1): 163-173. https://doi.org/10.3906/kim-1506-8

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