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Turkish Journal of Chemistry

DOI

10.3906/kim-1507-90

Abstract

Novel five-membered ($\kappa ^{2}-C,N)$-palladacyclic complexes were prepared from the reaction of the corresponding acetate-bridged palladacycle dimer with N-heterocyclic carbene (NHC) ligands in high yields. Palladacyclic complexes (3) were fully characterized by elemental analysis and $^{1}$H and $^{13}$C NMR spectroscopy. Palladacyclic complexes were tested as catalyst for the C-C bond forming reaction. These complexes were found to be efficient catalysts for the Suzuki-Miyaura reaction of aryl bromides.

First Page

1310

Last Page

1316

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