Turkish Journal of Chemistry
DOI
10.3906/kim-1408-71
Abstract
In this study peripherally tetra-substituted metal-free, metallophthalocyanines bearing (3,4-dimethoxybenzyl) oxy groups have been synthesized and characterized. Electrochemical properties of novel phthalocyanines 4, 5, 6, and 7 were determined by cyclic and square wave voltammetry in order to define their possible applications in different electrochemical technologies. Co^{II} and Ti^{IV}O metal ions behave as redox active cations in the core of the CoPc and TiOPc complexes, respectively. Voltammetric studies revealed that phthalocyanines have reversible/irreversible redox processes, which are the main requirement for the technological usage of these compounds.
Keywords
Phthalocyanine, oxotitanium, cobalt, electrochemistry, voltammetry
First Page
347
Last Page
358
Recommended Citation
ÖMEROĞLU, İPEK and BIYIKLIOĞLU, ZEKERİYA
(2015)
"Synthesis and electrochemistry of phthalocyanines bearing [(3,4-dimethoxybenzyl)oxy] groups,"
Turkish Journal of Chemistry: Vol. 39:
No.
2, Article 13.
https://doi.org/10.3906/kim-1408-71
Available at:
https://journals.tubitak.gov.tr/chem/vol39/iss2/13
