Synthesis and characterization of substituted benzimidazole Co(II), Fe(II), and Zn(II) complexes and structural characterization of dichlorobis{1-[2-(1-piperidinyl)ethyl]-1H-benzimidazole-_KN^3} zinc(II)

Authors

HASAN KÜÇÜKBAY
ÜLKÜ YILMAZ
MEHMET AKKURT
ORHAN BÜYÜKGÜNGÖR

Abstract

The Co(II), Fe(II), and Zn(II) complexes of 1-(3-phenyl)propylbenzimidazole (PPBI), 5-nitro-1-(3-phenyl) propylbenzimidazole (PPNBI), 1-[2-(4-morpholinyl)ethyl]benzimidazole (MEBI), 1-[2-(1-piperidinyl)ethyl]benzimidazole (PEBI), and 5-nitro-1-[2-(1-piperidinyl)ethyl]benzimidazole (PENBI) were synthesized and characterized by ^1H NMR, ^{13}C NMR, and elemental analyses. The magnitudes of the magnetic moments for paramagnetic complexes were between 4.07 and 5.11 B.M. Moreover, the crystal structure of dichlorobis{1-[2-(1-piperidinyl)ethyl]-1H-benzimidazole-_KN^3} zinc(II) was determined by single crystal X-ray diffraction.

DOI

10.3906/kim-1405-47

Keywords

Benzimidazole metal complexes, transition metal complexes, coordination compounds, crystal structure

First Page

108

Last Page

120

Recommended Citation

KÜÇÜKBAY, H, YILMAZ, Ü, AKKURT, M, & BÜYÜKGÜNGÖR, O (2015). Synthesis and characterization of substituted benzimidazole Co(II), Fe(II), and Zn(II) complexes and structural characterization of dichlorobis{1-[2-(1-piperidinyl)ethyl]-1H-benzimidazole-_KN^3} zinc(II). Turkish Journal of Chemistry 39 (1): 108-120. https://doi.org/10.3906/kim-1405-47