N-bridged dimers of tetrapyrroles complexed by transition metals: syntheses, characterization methods, and uses as oxidation catalysts

Authors

ÜMİT İŞCİ
FABIENNE DUMOULIN
ALEXANDER B. SOROKİN
VEFA AHSEN

DOI

10.3906/kim-1407-47

Abstract

N-bridged dimers of tetrapyrroles complexed by transition metals have been known for nearly four decades, and gained renewed attention when their powerful oxidation properties were recently evidenced. This article is a state of the art review of the reported complexes and of their synthetic methods. Beyond classical chemistry characterization tools, specific methods appropriate to their structure are used and are presented in detail. Finally, their uses and importance of oxidation catalysts are reviewed.

Keywords

Tetrapyrrole, porphyrin, phthalocyanine, transition metal, N-bridged dimeric complexes, \mu-nitrido, oxidation

First Page

923

Last Page

949

Recommended Citation

İŞCİ, ÜMİT; DUMOULIN, FABIENNE; SOROKİN, ALEXANDER B.; and AHSEN, VEFA (2014) "N-bridged dimers of tetrapyrroles complexed by transition metals: syntheses, characterization methods, and uses as oxidation catalysts," Turkish Journal of Chemistry: Vol. 38: No. 6, Article 2. https://doi.org/10.3906/kim-1407-47
Available at: https://journals.tubitak.gov.tr/chem/vol38/iss6/2