Synthesis and properties of novel polymeric metal-free and metallophthalocyanines containing peripherally long 1,2-bis[(3-oxapropyl)oxa]benzene derivatives

Authors

AHMET BİLGİN
DURMUŞ YANMAZ
ÇİĞDEM YAĞCI

DOI

10.3906/kim-1407-15

Abstract

New polymeric phthalocyanine moieties (M = 2H, Zn, Ni, Cu, and Co) were synthesized via polytetracyclomerization reaction of o-bis[3-(3,4-dicyanophenoxy)propyloxy]benzene (3), which can be obtained by the reaction of 4-nitrophthalonitrile with o-bis[(3-hydroxypropyl)oxy]benzene. Aggregation and disaggregation behavior of the polymeric phthalocyanine (5) was studied with some alkali and earth alkali metal cations. Measured intrinsic viscosities of the polymeric phthalocyanines exhibited a substantial decreasing tendency with dilution of the solution. Thermogravimetric analysis was performed under air by using DSC and DTG/TGA techniques and indicated that these polymers have good thermal stability. AC and DC electrical conductivities of the polymeric phthalocyanines were investigated in the frequency range 100 Hz--1 MHz within the temperature range 298--343 K. AC/DC conductivities of the samples were found to be between 10^{-5} and 10^{-7} S cm^{-1} at ambient temperature under argon atmosphere. The structures of new synthesized compounds were characterized by using microanalysis; various spectroscopic methods such as UV-Vis, FT-IR, ^1H NMR, and ^{13}C NMR spectroscopy; and MS spectra.

Keywords

Polymeric phthalocyanine, metallophthalocyanines, aggregation, AC/DC electrical conductivities, thermal properties, DSC/TGA

First Page

1135

Last Page

1152

Recommended Citation

BİLGİN, AHMET; YANMAZ, DURMUŞ; and YAĞCI, ÇİĞDEM (2014) "Synthesis and properties of novel polymeric metal-free and metallophthalocyanines containing peripherally long 1,2-bis[(3-oxapropyl)oxa]benzene derivatives," Turkish Journal of Chemistry: Vol. 38: No. 6, Article 17. https://doi.org/10.3906/kim-1407-15
Available at: https://journals.tubitak.gov.tr/chem/vol38/iss6/17