Synthesis and characterization of novel 2-{[2-(dimethylamino)ethyl](methyl)amino} ethoxy-substituted metallophthalocyanines

Authors

HİLAL ZENGİN
HACER YASEMİN YENİLMEZ
AYFER KALKAN BURAT
ZEHRA ALTUNTAŞ BAYIR

Abstract

The synthesis of novel, symmetrical, tetrasubstituted metallophthalocyanines (cobalt, zinc, and copper) bearing four 2-{[2-(dimethylamino)ethyl](methyl)amino} ethoxy units was reported. The dinitrile derivative was converted into the water-soluble quaternized product by its reaction with methyl iodide. The quaternized zinc phthalocyanine was obtained from the reaction of the water-soluble dinitrile derivative with zinc acetate. The structures of the newly synthesized molecules were proposed according to elemental analysis, ^1H NMR, FT-IR, and UV-Vis spectral data.

DOI

10.3906/kim-1405-26

Keywords

Phthalocyanine, 2-{[2(dimethylamino)ethyl]-methylamino} ethanol, water-soluble

First Page

1094

Last Page

1101

Recommended Citation

ZENGİN, H, YENİLMEZ, H. Y, BURAT, A. K, & BAYIR, Z. A (2014). Synthesis and characterization of novel 2-{[2-(dimethylamino)ethyl](methyl)amino} ethoxy-substituted metallophthalocyanines. Turkish Journal of Chemistry 38 (6): 1094-1101. https://doi.org/10.3906/kim-1405-26