Synthesis and characterization of novel 2-{[2-(dimethylamino)ethyl](methyl)amino} ethoxy-substituted metallophthalocyanines

Authors

HİLAL ZENGİN
HACER YASEMİN YENİLMEZ
AYFER KALKAN BURAT
ZEHRA ALTUNTAŞ BAYIR

DOI

10.3906/kim-1405-26

Abstract

The synthesis of novel, symmetrical, tetrasubstituted metallophthalocyanines (cobalt, zinc, and copper) bearing four 2-{[2-(dimethylamino)ethyl](methyl)amino} ethoxy units was reported. The dinitrile derivative was converted into the water-soluble quaternized product by its reaction with methyl iodide. The quaternized zinc phthalocyanine was obtained from the reaction of the water-soluble dinitrile derivative with zinc acetate. The structures of the newly synthesized molecules were proposed according to elemental analysis, ^1H NMR, FT-IR, and UV-Vis spectral data.

Keywords

Phthalocyanine, 2-{[2(dimethylamino)ethyl]-methylamino} ethanol, water-soluble

First Page

1094

Last Page

1101

Recommended Citation

ZENGİN, HİLAL; YENİLMEZ, HACER YASEMİN; BURAT, AYFER KALKAN; and BAYIR, ZEHRA ALTUNTAŞ (2014) "Synthesis and characterization of novel 2-{[2-(dimethylamino)ethyl](methyl)amino} ethoxy-substituted metallophthalocyanines," Turkish Journal of Chemistry: Vol. 38: No. 6, Article 14. https://doi.org/10.3906/kim-1405-26
Available at: https://journals.tubitak.gov.tr/chem/vol38/iss6/14