Novel metal-free and metallophthalocyanines containing four 21-membered pentathiadiaza macrocycles: synthesis, characterization, and study of aggregation properties

Authors

HALİL ZEKİ GÖK
BERNA FARSAK
HÜLYA KELEŞ
MUSTAFA KELEŞ

Abstract

Metal-free phthalocyanine 3 and its metallophthalocyanine derivatives 4, 5, and 6 (M = Zn, Co, and Ni) substituted with four 21-membered pentathiadiaza macrocycles were synthesized and their structures identified by elemental analysis, IR, ^1H NMR, mass, and UV-Vis spectroscopy techniques. The aggregation properties of phthalocyanines 4, 5, and 6 were investigated in different solvents and at different concentrations of dimethylformamide.

DOI

10.3906/kim-1403-63

First Page

1073

Last Page

1082

Recommended Citation

GÖK, H. Z, FARSAK, B, KELEŞ, H, & KELEŞ, M (2014). Novel metal-free and metallophthalocyanines containing four 21-membered pentathiadiaza macrocycles: synthesis, characterization, and study of aggregation properties. Turkish Journal of Chemistry 38 (6): 1073-1082. https://doi.org/10.3906/kim-1403-63