Synthesis and electrochemical and spectroelectrochemical characterization of chloromanganese(III) phthalocyanines

Authors

MUKADDES ÖZÇEŞMECİ
ILGIN NAR
ESİN HAMURYUDAN

DOI

10.3906/kim-1405-43

Abstract

The synthesis of novel, symmetrical, tetrasubstituted manganese phthalocyanine complexes bearing 4 hexylthio, 2',3',4',5',6'-pentafluorobenzyloxy, 2',3',5',6'-tetrafluoro-4'-hexylthio-benzyloxy, and 2',3',5',6'-tetrafluoro-4'-pentoxy-benzyloxy units is reported. The new compounds have been characterized by using elemental analyses and UV-Vis, FT-IR, and mass spectroscopic data. The electrochemical properties of the manganese phthalocyanine complexes were investigated by cyclic and square wave voltammetry and the nature of the observed redox processes was studied by spectroelectrochemistry.

Keywords

Phthalocyanines, manganese, cyclic voltammetry, spectroelectrochemistry

First Page

1064

Last Page

1072

Recommended Citation

ÖZÇEŞMECİ, MUKADDES; NAR, ILGIN; and HAMURYUDAN, ESİN (2014) "Synthesis and electrochemical and spectroelectrochemical characterization of chloromanganese(III) phthalocyanines," Turkish Journal of Chemistry: Vol. 38: No. 6, Article 11. https://doi.org/10.3906/kim-1405-43
Available at: https://journals.tubitak.gov.tr/chem/vol38/iss6/11