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Turkish Journal of Chemistry

DOI

10.3906/kim-1308-19

Abstract

A novel [Pb_2(\mu-atrz)_2(\mu-CH_3COO)(CH_3COO)]_n (atrz = 3-amino-1,2,4-triazole) complex was synthesized and characterized by IR spectroscopy, thermogravimetric analysis, and single crystal X-ray diffraction. The molecular structure shows that the complex is a coordination polymer in which there are 2 different lead(II) ions with coordination number of 5, Pb(2), and, with a coordination number of 4, Pb(1). Each atrz acts as a bridging ligand between 2 Pb(II) ions through the 2 adjacent nitrogen atoms of the triazole ring. The acetate anions show different types of coordination mode: one acts as a bridge by coordination of the same oxygen atom with Pb(II) ions and the other as a monodentate coordination by one of the oxygen atoms with Pb(2).

Keywords

3-Amino-1, 2, 4-triazole, 1, 2, 4-triazole, acetate, lead(II) complexes, coordination polymer

First Page

671

Last Page

678

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