Self-condensation reactions of acyl phosphonates: synthesis of tertiary O-protected \alpha-hydroxyphosphonates

Authors

SERKAN EYMUR
MEHMET GÖLLÜ
AYHAN SITKI DEMİR

DOI

10.3906/kim-1306-7

Abstract

The self-condensation reaction of benzoyl dialkyl phosphonates was developed using cyanide ion as catalyst, affording versatile tertiary O-protected \alpha-hydroxy phosphonates in moderate yield.

Keywords

Acyl phosphonates, tertiary \alpha-hydroxy phosphonates, phosphonate-phosphate rearrangement

First Page

164

Last Page

171

Recommended Citation

EYMUR, SERKAN; GÖLLÜ, MEHMET; and DEMİR, AYHAN SITKI (2014) "Self-condensation reactions of acyl phosphonates: synthesis of tertiary O-protected \alpha-hydroxyphosphonates," Turkish Journal of Chemistry: Vol. 38: No. 1, Article 17. https://doi.org/10.3906/kim-1306-7
Available at: https://journals.tubitak.gov.tr/chem/vol38/iss1/17