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Turkish Journal of Chemistry

Abstract

The Cu(I)-based complex prepared from (S)-2-(furan-2-yl-methylamino)-2-phenylethanol (5c) and CuCl was used as catalyst in enantioselective Henry reactions of arylaldehydes and nitromethane, which gave 89% ee and 95% yield at ambient temperature. The proposed catalytic cycle of an asymmetric Henry reaction was suggested.

DOI

10.3906/kim-1210-62

Keywords

Chiral amino alcohol, copper(I) salt, asymmetric catalysis, Henry reaction

First Page

966

Last Page

977

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