Turkish Journal of Chemistry
Abstract
Nitrile imines generated by the oxidative dehydrogenation of aromatic aldehyde phenylhydrazones with chloramine-T as a catalytic dehydrogenating agent were trapped in situ by 4-methoxy cinnamonitrile to afford 3,4-diaryl-1-phenyl-4,5-dihydro-1H-pyrazole-5-carbonitrile in moderate to good yields. The structures of the cycloadducts were confirmed by spectral studies and elemental analysis.
DOI
10.3906/kim-1209-52
Keywords
Pyrazoles, nitrile imines, chloramine-T, dipolar, cycloaddition
First Page
853
Last Page
857
Recommended Citation
PRABHASHANKAR, J, GOVINDAPPA, V. K, & KARIYAPPA, A. K (2013). Synthesis of 3,4-diaryl-1-phenyl-4,5-dihydro-1H-pyrazole-5-carbonitriles via 1,3-dipolar cycloaddition reactions. Turkish Journal of Chemistry 37 (5): 853-857. https://doi.org/10.3906/kim-1209-52
