Synthesis of novel tetraoxime derivative with hydrazone side groups and its metal complexes

Authors

İLKNUR BABAHAN
HÜSEYİN ANIL
NURSABAH SARIKAVAKLI

DOI

10.3906/kim-1003-105

Abstract

In this study, the synthesis of a novel tetraoxime (LH_4) derivative containing hydrazone side groups, and its transition metal complexes with Ni(II), Cu(II), Co(II), and Zn(II) ions, were reported. The ligand was synthesized by reacting anti-glyoximehydrazine (GH_2) with terephthaldialdehyde. Polymeric complexes with Ni(II) and Co(II) and binuclear complexes with Cu(II) and Zn(II) of this tetraoxime were isolated. Structural assignments were supported by a combination of ^1H-NMR, ^{13}C-NMR, HMQC, FT-IR, UV-Vis, thermogravimetric analysis (TGA), molar conductances, elemental analyses, and magnetic susceptibility.

Keywords

Tetraoximes, hydrazone, transition metal complexes

First Page

613

Last Page

624

Recommended Citation

BABAHAN, İLKNUR; ANIL, HÜSEYİN; and SARIKAVAKLI, NURSABAH (2011) "Synthesis of novel tetraoxime derivative with hydrazone side groups and its metal complexes," Turkish Journal of Chemistry: Vol. 35: No. 4, Article 9. https://doi.org/10.3906/kim-1003-105
Available at: https://journals.tubitak.gov.tr/chem/vol35/iss4/9