Turkish Journal of Chemistry
Abstract
In this study, the synthesis of a novel tetraoxime (LH_4) derivative containing hydrazone side groups, and its transition metal complexes with Ni(II), Cu(II), Co(II), and Zn(II) ions, were reported. The ligand was synthesized by reacting anti-glyoximehydrazine (GH_2) with terephthaldialdehyde. Polymeric complexes with Ni(II) and Co(II) and binuclear complexes with Cu(II) and Zn(II) of this tetraoxime were isolated. Structural assignments were supported by a combination of ^1H-NMR, ^{13}C-NMR, HMQC, FT-IR, UV-Vis, thermogravimetric analysis (TGA), molar conductances, elemental analyses, and magnetic susceptibility.
DOI
10.3906/kim-1003-105
Keywords
Tetraoximes, hydrazone, transition metal complexes
First Page
613
Last Page
624
Recommended Citation
BABAHAN, İ, ANIL, H, & SARIKAVAKLI, N (2011). Synthesis of novel tetraoxime derivative with hydrazone side groups and its metal complexes. Turkish Journal of Chemistry 35 (4): 613-624. https://doi.org/10.3906/kim-1003-105
