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Turkish Journal of Chemistry

DOI

10.3906/kim-1103-19

Abstract

Mild and efficient enantioselective Henry reactions of nitromethane with various aldehydes were catalyzed by a novel L-(+)-aspartic acid-derived Schiff base ligand in the presence of Cu(II) ions, affording the corresponding adducts in high yields (up to 96%) and enantioselectivities (up to 92% ee).

Keywords

Enantioselective Henry reaction, chiral Schiff base, L-(+)-aspartic acid

First Page

553

Last Page

560

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