Picolyl substituted N-heterocyclic carbene/palladium catalyzed Heck reactions

Authors

MURAT YİĞİT
BEYHAN YİĞİT
İSMAİL ÖZDEMİR
ENGİN ÇETİNKAYA

Abstract

Novel 1,3-dialkylimidazolinium and 1,3- dialkyltetrahydropyrimidinium hexafluorophosphate salts as N-heterocyclic carbene precursors were prepared by reacting N,N'-dialkylethandiamine or N,N'-dialkylpropandiamine, triethyl orthoformate, and ammonium hexafluorophosphate. The salts were characterized spectroscopically and tested in homogeneous Heck reactions.

DOI

10.3906/kim-0906-69

Keywords

Heck reaction, imidazolinium salt, palladium, carbene, catalyst.

First Page

327

Last Page

334

Recommended Citation

YİĞİT, MURAT; YİĞİT, BEYHAN; ÖZDEMİR, İSMAİL; and ÇETİNKAYA, ENGİN (2010) "Picolyl substituted N-heterocyclic carbene/palladium catalyzed Heck reactions," Turkish Journal of Chemistry: Vol. 34: No. 3, Article 1. https://doi.org/10.3906/kim-0906-69
Available at: https://journals.tubitak.gov.tr/chem/vol34/iss3/1