Abstract

Novel 1,3-dialkylimidazolinium and 1,3- dialkyltetrahydropyrimidinium hexafluorophosphate salts as N-heterocyclic carbene precursors were prepared by reacting N,N'-dialkylethandiamine or N,N'-dialkylpropandiamine, triethyl orthoformate, and ammonium hexafluorophosphate. The salts were characterized spectroscopically and tested in homogeneous Heck reactions.

DOI

10.3906/kim-0906-69

Keywords

Heck reaction, imidazolinium salt, palladium, carbene, catalyst.

First Page

327

Last Page

334

Recommended Citation

YİĞİT, M, YİĞİT, B, ÖZDEMİR, İ, & ÇETİNKAYA, E (2010). Picolyl substituted N-heterocyclic carbene/palladium catalyzed Heck reactions. Turkish Journal of Chemistry 34 (3): 327-334. https://doi.org/10.3906/kim-0906-69

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