Picolyl substituted N-heterocyclic carbene/palladium catalyzed Heck reactions

Authors

MURAT YİĞİT
BEYHAN YİĞİT
İSMAİL ÖZDEMİR
ENGİN ÇETİNKAYA

DOI

10.3906/kim-0906-69

Abstract

Novel 1,3-dialkylimidazolinium and 1,3- dialkyltetrahydropyrimidinium hexafluorophosphate salts as N-heterocyclic carbene precursors were prepared by reacting N,N'-dialkylethandiamine or N,N'-dialkylpropandiamine, triethyl orthoformate, and ammonium hexafluorophosphate. The salts were characterized spectroscopically and tested in homogeneous Heck reactions.

Keywords

Heck reaction, imidazolinium salt, palladium, carbene, catalyst.

First Page

327

Last Page

334

Recommended Citation

YİĞİT, MURAT; YİĞİT, BEYHAN; ÖZDEMİR, İSMAİL; and ÇETİNKAYA, ENGİN (2010) "Picolyl substituted N-heterocyclic carbene/palladium catalyzed Heck reactions," Turkish Journal of Chemistry: Vol. 34: No. 3, Article 1. https://doi.org/10.3906/kim-0906-69
Available at: https://journals.tubitak.gov.tr/chem/vol34/iss3/1