Highly stereoselective and efficient synthesis of the dopa analogue in pepticinnamin E via enantioselective hydrogenation of dehydroamino acids

Authors

DEQUN SUN

DOI

10.3906/kim-0904-14

Abstract

An efficient and new method was developed to prepare the dopa analogue 11 in natural pepticinnamin via catalytic hydrogenation of dehydroamino acids (DDAA) with a good yield and ee. Product 11 is a key intermediate towards the total synthesis of pepticinnamin E and its analogues.

Keywords

Synthesis; dopa analogue; enantioselective hydrogenation; dehydroamino acid.

First Page

181

Last Page

186

Recommended Citation

SUN, DEQUN (2010) "Highly stereoselective and efficient synthesis of the dopa analogue in pepticinnamin E via enantioselective hydrogenation of dehydroamino acids," Turkish Journal of Chemistry: Vol. 34: No. 2, Article 3. https://doi.org/10.3906/kim-0904-14
Available at: https://journals.tubitak.gov.tr/chem/vol34/iss2/3