Highly stereoselective and efficient synthesis of the dopa analogue in pepticinnamin E via enantioselective hydrogenation of dehydroamino acids

Authors

DEQUN SUN

Abstract

An efficient and new method was developed to prepare the dopa analogue 11 in natural pepticinnamin via catalytic hydrogenation of dehydroamino acids (DDAA) with a good yield and ee. Product 11 is a key intermediate towards the total synthesis of pepticinnamin E and its analogues.

DOI

10.3906/kim-0904-14

Keywords

Synthesis; dopa analogue; enantioselective hydrogenation; dehydroamino acid.

First Page

181

Last Page

186

Recommended Citation

SUN, DEQUN (2010) "Highly stereoselective and efficient synthesis of the dopa analogue in pepticinnamin E via enantioselective hydrogenation of dehydroamino acids," Turkish Journal of Chemistry: Vol. 34: No. 2, Article 3. https://doi.org/10.3906/kim-0904-14
Available at: https://journals.tubitak.gov.tr/chem/vol34/iss2/3