Turkish Journal of Chemistry
Synthesis and characterization of non-symmetric tetradentate complexes of Zn(II), Co(II), and Cu(II)
Abstract
The non-symmetrical tetradentate Schiff-base H_2L was obtained using the half-unit N-(1-hydroxy-2-acetophenone)-1-amino- 2-phenyleneimine (HL) with 2-hydroxyl-1-naphthaldehyde. ZnL, CoL, and CuL complexes were prepared and characterized by ^1H-NMR, IR, electronic, and atomic absorption spectra. The single crystal X-ray structure of CuL was determined. Crystal data for CuL are triclinic space group P-1, a = 8.3933 (17) Å, b = 11.197 (2) Å, c = 13.381 (3) Å, \alpha = 95.29 (3)°, \beta = 94.37 (3)°, \gamma = 95.82 (3)°, and z = 2.
DOI
10.3906/kim-0811-31
First Page
263
Last Page
268
Recommended Citation
LASHANIZADEGAN, M, & SERAJ, S (2010). Synthesis and characterization of non-symmetric tetradentate complexes of Zn(II), Co(II), and Cu(II). Turkish Journal of Chemistry 34 (2): 263-268. https://doi.org/10.3906/kim-0811-31
