Turkish Journal of Chemistry
DOI
10.3906/kim-0901-1
Abstract
N,N-dimethyl-N' -(2-methylbenzoyl)thiourea, C_{11}H_{14}N_2SO (HL^1), N,N-dibutyl-N' -(2-methylben\-zoyl)thiourea, C{17}H{26}N2SO (HL^2), and N,N-dihexyl-N' -(2-methylbenzoyl) thiourea, C{21}H{34}N2SO (HL^3) were synthesized and characterized by elemental analysis, spectroscopic methods (FT-IR, NMR), and single crystal X-ray diffraction. Compound HL^1 crystallizes in the monoclinic system, space group P21/c, Z = 4. Compound HL^3 also crystallizes in the monoclinic system, space group P21/n, Z = 8 with 2 independent molecules in the asymmetric unit. Compound HL^2 crystallizes in the orthorhombic system, space group Pcnn, Z = 8. In all compounds, molecules form dimers through the strong intermolecular N-H...S hydrogen bonds. Moreover, there are different types of intra- and inter-molecular interactions in the crystal structures, and so the molecules of the 3 compounds also pack differently.
Keywords
Thiourea derivatives, benzoylthioureas, single crystal X-ray structures.
First Page
857
Last Page
868
Recommended Citation
KAVAK, GÜLTEN; ÖZBEY, SÜHEYLA; BİNZET, GÜN; and KÜLCÜ, NEVZAT
(2009)
"Synthesis and single crystal structure analysis of three novel benzoylthiourea derivatives,"
Turkish Journal of Chemistry: Vol. 33:
No.
6, Article 13.
https://doi.org/10.3906/kim-0901-1
Available at:
https://journals.tubitak.gov.tr/chem/vol33/iss6/13
