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Turkish Journal of Chemistry

DOI

10.3906/kim-0801-24

Abstract

Treatment of N,N-bis(2-hydroxybenzyl)-2-(2-aminoethyl) dimethylamine (H_2had) with trans-[ReO_2(py)_4]I in acetone affords the iodide salts of the oxypyridinium-ammonium zwitterions N^1-(2-hydroxybenzyl)-N^2,N^2-dimethyl-N^1-((2-oxypyridinium)-1- methyl)ethane-1,2-diamine [Hhpd]^+ and N^2,N^2-dimethyl-N^1- bis((2-oxypyridinium)-1- methyl)ethane-1,2-diamine [dod]^+. The products were characterized by X-ray structure analysis, and NMR and IR spectroscopy.

First Page

569

Last Page

577

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