Turkish Journal of Chemistry
DOI
10.3906/kim-0810-52
Abstract
The photobromination of substituted indan derivatives was studied. Four products, 2,3-dibromo-inden-1-one (5), trans-2,3-dibromoindan-1-one (6), 2,2-dibromoindan-1,3-dione (7) and 2,2-dibromoindan-1-one (8), were obtained by the bromination of indan-1-one (4). The bromination of 2-methyl indanone (9) and 3-methyl-indanone (13) gave the corresponding monobromo, dibromo, and tribromo compounds in high yield. 4-Nitro indan (16) was tribrominated under same condition reaction. The structures of these products were determined from ^1H-NMR, ^{13}C-NMR, MS, and IR data.
Keywords
Indan-1-one, 2-methyl-1-indanone, 3-methly-1-indanone, 4-nitro indan.
First Page
479
Last Page
486
Recommended Citation
KUŞ, NERMİN ŞİMŞEK
(2009)
"Photochemical bromination of substituted indan-1-one derivatives: synthesis of new polybromoindan-1-one derivatives,"
Turkish Journal of Chemistry: Vol. 33:
No.
4, Article 5.
https://doi.org/10.3906/kim-0810-52
Available at:
https://journals.tubitak.gov.tr/chem/vol33/iss4/5
