[Pd(Me-Xanthate)_2]: Synthesis, Characterization, and X-Ray Structure

Authors

SAIRA SHAHZADI
SAQIB ALI
REHANA JABEEN
MUHAMMAD KALEEM KHOSA

DOI

10.3906/kim-0802-1

Abstract

Potassium methyl xanthate and its complex [Pd(Me-Xanthate)_2] were synthesized at room temperature under stirring conditions. The ligand and the complex were characterized by elemental analysis, IR, NMR (^1H, ^{13}C) and XRD. NMR data revealed that potassium methyl xanthate acts as a bidentate specie and the complex exhibits 4-coordinated geometry in solution. In solid state, the palladium atom is coordinated to the 2 sulfur atoms of the xanthate ligand and the complex exhibits distorted square planar geometry.

Keywords

Palladium(II) xanthate, spectroscopy, X-ray structure

First Page

307

Last Page

312

Recommended Citation

SHAHZADI, SAIRA; ALI, SAQIB; JABEEN, REHANA; and KHOSA, MUHAMMAD KALEEM (2009) "[Pd(Me-Xanthate)_2]: Synthesis, Characterization, and X-Ray Structure," Turkish Journal of Chemistry: Vol. 33: No. 2, Article 14. https://doi.org/10.3906/kim-0802-1
Available at: https://journals.tubitak.gov.tr/chem/vol33/iss2/14