Turkish Journal of Chemistry
DOI
-
Abstract
In this study, (hydroxyimino)(2-phenyl(1,2,3,4-tetrahydroquinazolin- 2-yl))methane (H_2L^1) and (hydroxyimino)(2-(2-thienyl)(1,2,3,4- tetrahydroquinazolin-2-yl))methane (H_2L^2) were synthesized by the condensation of 2-(hydroxyimino)-1-phenylethan-1-one (INAP) and 2-(hydroxyimino)-1-(2-thienyl)ethan-1-one (INAT) with 2-aminobenzylamine (2-ABA). Complexes of these ligands with Co^{3+} were prepared with a metal:ligand ratio of 1:2. The ligands and their complexes were elucidated on the basis of elemental analyses, AAS, FT-IR, ^1H- and ^{13}C-NMR spectra, mass spectra, magnetic susceptibility measurements, and molar conductivity.
Keywords
1, 2, 3, 4-tetrahydroquinazoline, tetrahydroquinazoline oxime, iminooxime, Schiff bases, cobalt(III) complexes.
First Page
731
Last Page
741
Recommended Citation
MUTLU, HASENE and İREZ, GAZİ (2008) "Synthesis and Characterization of New Tridentate Iminooxime Ligands and Their Co(III) Complexes," Turkish Journal of Chemistry: Vol. 32: No. 6, Article 9. Available at: https://journals.tubitak.gov.tr/chem/vol32/iss6/9
