Turkish Journal of Chemistry
Abstract
In this study, (hydroxyimino)(2-phenyl(1,2,3,4-tetrahydroquinazolin- 2-yl))methane (H_2L^1) and (hydroxyimino)(2-(2-thienyl)(1,2,3,4- tetrahydroquinazolin-2-yl))methane (H_2L^2) were synthesized by the condensation of 2-(hydroxyimino)-1-phenylethan-1-one (INAP) and 2-(hydroxyimino)-1-(2-thienyl)ethan-1-one (INAT) with 2-aminobenzylamine (2-ABA). Complexes of these ligands with Co^{3+} were prepared with a metal:ligand ratio of 1:2. The ligands and their complexes were elucidated on the basis of elemental analyses, AAS, FT-IR, ^1H- and ^{13}C-NMR spectra, mass spectra, magnetic susceptibility measurements, and molar conductivity.
DOI
-
Keywords
1, 2, 3, 4-tetrahydroquinazoline, tetrahydroquinazoline oxime, iminooxime, Schiff bases, cobalt(III) complexes.
First Page
731
Last Page
741
Recommended Citation
MUTLU, H, & İREZ, G (2008). Synthesis and Characterization of New Tridentate Iminooxime Ligands and Their Co(III) Complexes. Turkish Journal of Chemistry 32 (6): 731-741. https://doi.org/-
